含糊其辞 发表于 2025-3-23 12:54:29
Path Probability Method as Applied to Problems of Superionic Conductions known as a substantial sublattice disorder or a “liquid sublattice.”. The large ionic conductivity is due to a mass motion of a large number of diffusing ions in the liquid sublattice. The problems of superionic conduction can therefore be reduced to elucidating the following two fundamental problMonocle 发表于 2025-3-23 16:34:02
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Vibration Effect in the Order-Disorder Transition Theory of RbAg4I5I., we have studied the effect of vibrational frequency differences on the equilibrium distribution of Ag. ions. It is found that one could introduce a considerable error by neglecting the above mentioned effect.concentrate 发表于 2025-3-24 05:12:10
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A Microscopic Model for Sublattice Disorder in Ionic Crystalsystals.. A microscopic model for the energy of disorder has been derived by adapting an approximate theory for the energy of formation of isolated point defects to the case of large defect concentrations. The model, which is a modification of the Mott-Littleton theory of point defect energetics, tak红润 发表于 2025-3-24 14:18:04
Minimum Energy Path Model Calculation for Several Fast Ionic Conductorsed to treat the tetragonal rutile and cubic fluorite structures. The results of these calculations and their relevance to experimental observations in a number of fast ionic conductors will be discussed.Seizure 发表于 2025-3-24 15:27:51
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Path Probability Method as Applied to Problems of Superionic Conductionthe “liquid sublattice” are specified. As such, the treatment is a generalization of the random walk theory of diffusion which is only applicable when the number of defects through which ions can move is extremely small.HILAR 发表于 2025-3-25 02:35:43
Superionic Conductivity and Order-Disorder Transitiongh the distribution of anions and vacancies on the SC sublattice itself is not affected by the transition..The basic cluster used in the Path Probability method is the double tetrahedron of the FCC sublattice in which a . sit.