infelicitous 发表于 2025-3-25 06:10:01

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吞下 发表于 2025-3-25 11:24:48

Substituent Effects on the CC-Bond Strength.,Stabilization energies for a series of carbon radicals substituted in the α-position by -CN, -OCH. and -SCH. were determined by a combination of kinetic and thermochemical methods and EFF calculations. The data are discussed in the context of substituent effects in free radical chemistry, in general.

Functional 发表于 2025-3-25 15:30:32

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Rodent 发表于 2025-3-25 17:55:17

https://doi.org/10.1007/978-94-009-4758-0Cycloaddition; Hyperconjugation; Nucleophilic substitution; Rearrangement; Steric effect

abysmal 发表于 2025-3-25 22:07:54

978-94-010-8614-1D. Reidel Publishing Company, Dordrecht, Holland 1986

1分开 发表于 2025-3-26 00:58:57

Substituent Effects in Radical Chemistry978-94-009-4758-0Series ISSN 1389-2185

猛然一拉 发表于 2025-3-26 07:24:41

1389-2185 Overview: 978-94-010-8614-1978-94-009-4758-0Series ISSN 1389-2185

丰满中国 发表于 2025-3-26 08:43:01

ESR-Spectroscopical Investigation of Capto-Dative Substituent Effects in Benzyl Radicals,ed in terms of substituent-induced spin delocalization. On the basis of the dependence of radical stabilization on spin delocalization it is concluded that capto-dative substitution implies a synergetic substituent effect on radical stabilization, whereas antagonistic effects are observed in the case of two identical substituents.

贪婪的人 发表于 2025-3-26 14:28:37

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公理 发表于 2025-3-26 20:14:10

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查看完整版本: Titlebook: Substituent Effects in Radical Chemistry; Heinz G. Viehe,Zdenek Janousek,Robert Merényi Book 1986 D. Reidel Publishing Company, Dordrecht,