EXCEL 发表于 2025-3-26 22:43:50
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,Asymmetric Synthesis via (α-Haloalkyl)boronic Esters,99% enantiomeric excess. Several adjacent chiral centers and a wide variety of functional groups can be incorporated into the target compounds. The only restrictions are those imposed by high steric hindrance and reactive functionality.Suggestions 发表于 2025-3-27 16:21:38
978-3-642-79711-8Springer-Verlag Berlin Heidelberg 1995notification 发表于 2025-3-27 17:52:12
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Reactivity and Structure: Concepts in Organic Chemistryhttp://image.papertrans.cn/s/image/877364.jpglanugo 发表于 2025-3-28 08:05:57
https://doi.org/10.1007/978-3-642-79709-5Aldehyde; Ketone; alkene; carbon; chirality; coupling reaction; metals; olefine; organometallic chemistry; ox简略 发表于 2025-3-28 11:02:37
Alkenylboranes and Control of Olefinic Geometry, nucleofuge, such as halide, alkoxide, amino, or alkylthio. The other is via direct electrophilic replacement of boron from an alkenylborane. Many known examples in the first category derive the stereospecifically β-substituted borane from an alkenylborane, though there are significant exceptions that will be noted.