最初
发表于 2025-3-28 14:48:47
Deuterium Labelling Studies of Cation Radicalsand difficulties with their generation have been obstacles to the study of representative organic and inorganic cation radicals This changed with the development of halocarbon and noble gas matrix isolation techniques combined with ionizing radiations as applied to ESR spectroscopy by Shida [.] and
farewell
发表于 2025-3-28 22:33:44
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套索
发表于 2025-3-29 01:44:19
Study of Radical Cations by Time-Resolved Magnetic Resonancerly chemical events induced by ionizing or photoionizing radiation. The development of specialized time-resolved magnetic resonance tools has allowed us to dispense with a key element that has been vital to a wide range of radical cation studies using static EPR, i.e., a stabilizing (rigid, chemical
打击
发表于 2025-3-29 04:38:18
Radical Cations in Pulse Radiolysis are usually very reactive. In condensed matter radical cations interact with their neighboring molecules forming solvation shells. This is also important for cations in non-polar liquids. Solvation of the cations occurs probably within picoseconds. For liquids such as alkanes or carbon tetrachlorid
凝结剂
发表于 2025-3-29 09:44:17
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kindred
发表于 2025-3-29 13:40:18
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vector
发表于 2025-3-29 19:25:18
Trapped Anions in Organic Crystalspy. The study makes it possible to precisely determine ESR parameters such as g, hyperfine, and quadrupole tensors. The geometrical and electronic structures of the radicals can be deduced from these parameters by comparing the tensor axes with the molecular orientation in the crystals. Analysis of
CHAR
发表于 2025-3-29 21:05:46
Anion Radicals in Inorganic Crystalss with polyatomic ions yielded well-resolved ESR signals after exposure to ionizing radiation. The ESR signals were initially assigned to paramagnetic ‘centers’ in analogy with the results of previous studies of radiation damage in alkali halides. It eventually became apparent, however, that the obs
Friction
发表于 2025-3-30 00:21:41
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致命
发表于 2025-3-30 04:56:50
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