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Francis A. Carey,Richard J. Sundberg eignet sich hervorragend zur Vorbereitung auf das technische Studium an Fachhochschulen. Das didaktische Konzept, den Stoff anwendungsorientiert zu vermitteln, zieht sich konsequent durch das ganze Buch. Viele Beispielaufgaben mit sehr ausführlichem Lösungsweg ermöglichen ein sicheres Nachvollziehe
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Reaction of Carbon Nucleophiles with Carbonyl Groups,begin by the addition of a carbon nucleophile to a carbonyl group. The product which is isolated depends on the nature of the substituent (X) on the carbon nucleophile, the substituents (A and B) on the carbonyl group, and the ways in which A, B, and X interact to control the reaction pathways avail
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Functional Group Interconversion by Nucleophilic Substitution,lectrophile. In this chapter, we turn our attention to noncarbon nucleophiles. Nucleophilic substitution at both .. and .. centers is used in a variety of synthetic operations, particularly in the inverconversion of functional groups. The mechanistic aspects of nucleophilic substitutions were consid
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Electrophilic Additions to Carbon-Carbon Multiple Bonds,restricted to reactions which proceed through polar intermediates or transition states. Several other classes of addition reactions are also of importance, and these are discussed elsewhere. Nucleophilic additions to electrophilic alkenes were covered in Chapter 1, and cycloadditions involving conce
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Reduction of Carbonyl and Other Functional Groups,ncluding addition of hydrogen and/or electrons to a molecule or removal of oxygen or other electronegative substituents. The most important reducing agents from a synthetic point of view are molecular hydrogen and hydride derivatives of boron and aluminum. Other important procedures use metals such
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Reactions Involving the Transition Metals, metals are also very important. In this chapter, we will discuss reactions which are important in synthetic organic chemistry that involve transition-metal compounds and intermediates. In contrast to reactions involving lithium and magnesium, in which the organometallic reagents are used in stoichi