埋伏 发表于 2025-3-28 17:50:31
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http://reply.papertrans.cn/71/7053/705295/705295_42.pngminimal 发表于 2025-3-29 01:44:55
Homopolar Bonds and Catenation,The whole concept of oxidation states is the least adaptable to this situation. Nobody would expect an essential difference between the chemical bonding in methane CH. and ethane C.H.. This means that two of the eighteen electrons of the ethane molecule must be so firmly occupied by forming a singlePillory 发表于 2025-3-29 04:17:16
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Taxological Quantum Chemistry,uation for the one-electron system H.. Even before the simplest problems of chemical bonding could be tackled, it was already an admirable result to have rationalized the energy levels of atoms and monatomic positive ions. Cynical people may argue that the atomic spectroscopists already had taken ca激怒某人 发表于 2025-3-29 13:54:16
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id explanation was available of the colours of compounds of the five tran sition groups. Later, it was possible to identify the excited levels with those expected for an electron configuration with adefinite number of electrons in the partly filled shell. I t is not generally recognized that this i盟军 发表于 2025-3-29 20:51:12
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Inter-Shell Transitions,upation number at the same time indicate somewhat different spatial extension of the different sub-shells. However, the agreement of the spectra of octahedral complexes with the Tanabe-Sugano diagrams shows that the characteristics of the partly filled d-shell are retained to a large degree.