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Selenium-Stabilized Carbanions,to .-selanyl vinylmetals is considered. Besides the classical methods involving vinylic selenides and ketene selenoacetals, the hydrometallation (M = Sn, Zr, B) of acetylenic selenides constitutes an efficient method. These species can be considered as vinyl dianion equivalents. Some examples of cross-coupling reactions are presented.才能 发表于 2025-3-22 05:35:59
Nucleophilic Selenium,cleophilic selenium are summarized. In addition, applications of nucleophilic selenium to asymmetric and solid-phase syntheses are presented separately. These new attempts are further increasing the intriguing utility of the nucleophilic selenium species.冬眠 发表于 2025-3-22 10:43:55
Selenocarbonyls,r syntheses and reactions are classified on the basis of reaction patterns rather than the substituents adjacent to selenocarbonyl group. Several types of metal complexes having selenocarbonyl groups are described as well.Cholesterol 发表于 2025-3-22 14:11:12
Radical Reactions Using Selenium Precursors, for the formation of carbon-carbon bonds and carbon-heteroatom bonds. Selenols and diselenides have found applications as reducing agents and radical traps, respectively. A survey of these different reaction types will be given. Information about new reactions based on electron and photoelectron transfers will also be provided.展览 发表于 2025-3-22 17:44:14
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