摇摆 发表于 2025-3-26 21:20:42

Donor-Acceptor-Substituted Cyclopropanes via Fischer Carbene Complexes,lopropanes in good yields. Scope and limitations of this -cycloaddition are described. Certain α,β-unsaturated nitriles suffer an insertion of the carbene into the C=N-bond to give new vinyl-substituted carbene complexes. The mechanism of this insertion reaction as well as that of the -cycloaddition are discussed.

aptitude 发表于 2025-3-27 02:01:26

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observatory 发表于 2025-3-27 08:27:30

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FECT 发表于 2025-3-27 13:04:52

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辩论的终结 发表于 2025-3-27 17:25:04

,Directed — and Undirected — Syntheses of Novel Organic Compounds via Iron, Cobalt and Chromium CompOrganometaliic compounds may be extremely useful intermediates in organic synthesis in a number of ways. In fact, with the help of metals and metal complexes one can bring about transformations, which cannot otherwise be achieved.. In this respect, we have started to engage in organometallic chemistry from three different viewpoints:

Foolproof 发表于 2025-3-27 20:24:28

Enantioselective Synthesis of Organic Compounds with Optically Active Transition Metal Catalysts anMetabolism in man, animal and plant uses optically active compounds, e.g. L-amino acids, D-sugars etc. This metabolic stereospecificity manifests itself in macroscopic chiral structures such as snail shells, in which high stereoselectivities are observed. Other examples for plants are shown in Fig. 1.

LAVE 发表于 2025-3-28 01:21:12

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Recess 发表于 2025-3-28 02:33:17

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驾驶 发表于 2025-3-28 06:50:07

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octogenarian 发表于 2025-3-28 11:35:09

Overview: 978-3-540-50531-0978-3-642-74269-9
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查看完整版本: Titlebook: Organometallics in Organic Synthesis 2; Aspects of a Modern Helmut Werner,Gerhard Erker Conference proceedings 1989 Springer-Verlag Berlin