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Geometry and Magnetism of Lanthanide Compounds,lanthanide ions. Here, we focus on the representative Ln-SMMs with different coordination geometries from the view of coordination numbers, discuss the methods of modulating ligand fields, highlight the importance of constructing predominant bonds, and explain the relationship between the geometry, crystal field, and molecular magnetisms.不幸的人 发表于 2025-3-28 05:19:10
Role of Ab Initio Calculations in the Design and Development of Lanthanide Based Single Molecule Manonuclear Dy. SIMs, we have also covered other lanthanide SIMs briefly. Particularly, we have classified various SIMs based on the observed crystal-field splitting between ground and first excited states and this likely to shed light on the most important issue of suitable geometries that could yield high blocking temperature SIMs.AWRY 发表于 2025-3-28 08:44:17
Book 2019ic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, lumiWater-Brash 发表于 2025-3-28 11:12:28
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