mucous-membrane 发表于 2025-3-25 03:52:15
Electronic state effects in sigma bond activation by first row transition metal ions: the ion chromtant molecules . Both theory and experiment indicate the reactivity of a given state of the metal ion will depend on its interaction with other nearby electronic states. Surface crossings are commonplace and “spin-forbidden” reactions are often observed for transition metal ions (spin is generalnegotiable 发表于 2025-3-25 08:58:56
http://reply.papertrans.cn/71/7046/704517/704517_22.pngallergy 发表于 2025-3-25 13:44:33
Gas-phase thermochemistry of transition metal ligand systems: reassessment of values and periodic ttermine quantitative thermodynamic information for coordinatively unsaturated organometallic molecules. Gas-phase methods are particularly useful for studies of such species, which are highly reactive because they are not stable 18-e. complexes. This feature is used to advantage in examining the pertenuous 发表于 2025-3-25 18:02:32
http://reply.papertrans.cn/71/7046/704517/704517_24.pngPostmenopause 发表于 2025-3-25 22:08:08
http://reply.papertrans.cn/71/7046/704517/704517_25.png暗语 发表于 2025-3-26 02:59:56
http://reply.papertrans.cn/71/7046/704517/704517_26.pngpersistence 发表于 2025-3-26 04:32:09
Electronic state effects in sigma bond activation by first row transition metal ions: the ion chrom excited states available to the transition metal center. The details of the interactions of these metal ion states with the reactant molecule, however, are not well understood and the desire to understand these details has stimulated significant experimental and theoretical interest. On the experim整体 发表于 2025-3-26 09:19:30
http://reply.papertrans.cn/71/7046/704517/704517_28.pngDelirium 发表于 2025-3-26 13:27:42
http://reply.papertrans.cn/71/7046/704517/704517_29.pngmonopoly 发表于 2025-3-26 19:00:31
Applications of gas-phase electron-transfer equilibria in organometallic redox thermochemistry,ch is known about these intrinsic properties for atoms and organic molecules in the gas phase . Far fewer organometallic compounds have had their ionization energies determined and even fewer electron affinities are known for metal-containing molecules.