BRIEF
发表于 2025-3-25 07:01:39
The Band Structure of the One-Dimensional (Bisglyoximato)Ni(II) Systemtion of intracell and intercell interactions as a function of certain details of the stacking geometry. Ni(gly). has been the subject of tight-binding studies on the basis of the semiempirical INDO CO Hamiltonian that has been used as principal computational framework for the present lecture note [I
Concerto
发表于 2025-3-25 09:24:52
Band Structures of 1D (Porphyrinato)Ni(II) Systemsains (i.e. intercell separation), on one side, and electronic structure effects (i.e. torsional barriers, magnitude of intra- and intercell energies, charge distribution, etc.), on the other. One-dimensional (porphyrinato)NI(II) systems are suitable materials to quantify correlations between structu
relieve
发表于 2025-3-25 15:14:47
The 1D Band Structure of Tetrathiotetraceneon removal; the transfer paths are ligand-centered. In this section we discuss tetrathiotetracene, TTT, as its solid-state properties are comparable to those of low-dimensional organometallic 1D systems with ligand-centered charge-transfer channels. TTT is schematized in fig. IV.24 where also the st
不可救药
发表于 2025-3-25 19:11:49
The Band Structure of Polyferrocenylenephysical consequence of this type of hybridization is a strong k-dependence in the character of the CO microstates (i.e. correlation between localized metal-centered and delocalized ligand basis functions) in a given energy band. This is a solid-state phenomenon which is (frequently) not found in th
resistant
发表于 2025-3-25 22:58:55
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Heart-Rate
发表于 2025-3-26 02:46:21
Band Structures of 1D (Porphyrinato)Ni(II) Systemsen the subject of a number of experimental and theoretical studies. These 1D solids show significant changes in the nature of injected carriers, paramagnetic susceptibi1ities χ. and the temperature dependence of the electric conductivity σ as response to structural changes in the macrocyclic π ligand.
ADORN
发表于 2025-3-26 05:20:29
The Band Structure of Polyferrocenyleneat the transition—metal center. Trans polyferrocenylene, see fig. IV.26, is one member in a larger class of conducting or semiconducting materials that are formed by ferrocene-like units .
灾祸
发表于 2025-3-26 08:43:23
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Iatrogenic
发表于 2025-3-26 16:31:29
Book 1987s formed by transition-met. l atoms that are embedded in a matrix of macrocyclic organic ligands. These systems as well as orga nic metals have focused considerable interest due to the potential formation of high-mobility charge carriers. For the present author it is difficult to participate in thi
COST
发表于 2025-3-26 19:53:25
Partially Oxidized Transition-Metal Polymers; Stabilization of Mixed Valence Statesy Kunz and coworkers in simple narrow-band insulators of the Mott-Hubbard type. Energetic consequences of electron removal from localized orbitals of the Heitler-London type have been studied by elaborate computational methods .