树木中 发表于 2025-3-25 03:38:50
Mechanistic Insights into Surface-Supported Chemical Reactions,btain fascinating and unprecedented insights into the mechanisms of chemical transformations. Particularly exciting are recent advances in atomic force microscopy that allow bond-resolved imaging and thus make the chemical identification of organic molecular reaction intermediates and products possi沙草纸 发表于 2025-3-25 09:29:10
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Reactivity , and , Graphene Layers: Scanning Probe Microscopy Reveals,ng (STM) and atomic force microscopies (AFM). We place particular emphasis on the diversity of reactions, systems and synthetic strategies that are now available to surface scientists working in various fundamental and applied research fields. Using imine formation as the model reaction we discuss cHot-Flash 发表于 2025-3-25 15:56:40
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On-Surface Ullmann Reaction for the Synthesis of Polymers and Macrocycles,n situ characterizations of products with large molecular weight are required. This article covers the on-surface synthesis of hydrocarbon polymers and macrocycles via an Ullmann type reaction of haloarenes on metal single-crystal surfaces. The related formation of stable organometallic reaction int抱负 发表于 2025-3-26 03:47:24
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,Aryl–Aryl Covalent Coupling on Rutile TiO2 Surfaces,directly on a supporting surface. So far, selected noble metals have been mostly used as substrates for such on-surface chemical reactions. For the sake of practical applications the semiconductor surfaces clearly represent much more attractive platforms. Especially transition metal oxides exhibitin狗舍 发表于 2025-3-26 10:41:47
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On-Surface Coupling Reactions with Extrinsic Catalysts,e catalytic effects of Cu and Pd deposits in the on-surface Ullmann coupling and Sonogashira cross-coupling reactions. The stepwise reaction paths, intermediates, and activation energies are deliberated at a single molecular level using scanning tunneling microscopy (STM). Such studies offer mechani抱狗不敢前 发表于 2025-3-26 17:33:14
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