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,Structural Evolution under High Pressure and at High Temperature of a β’-Sialon Phase,nalysis technique, the structure is presented. Its evolution under high pressure and at high temperature is given in terms of motion of the . tetrahedra. This motion is compared with the motion in other nitrides or oxynitrides such as Si.N., AIN and Si.N.O of the SiN. and SiON. tetrahedra.