陪审团每个人 发表于 2025-3-23 11:56:37
Jean-Jacques Girerd,Frédéric Banse,Ariane Jalila SimaanSPASM 发表于 2025-3-23 14:45:51
Waldemar Adam,Catherine M. Mitchell,Chantu R. Saha-Möller,Oliver WeicholdAtheroma 发表于 2025-3-23 19:24:07
Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations散步 发表于 2025-3-23 23:30:47
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0081-5993 . The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.978-3-662-15663-6978-3-540-46592-8Series ISSN 0081-5993 Series E-ISSN 1616-8550HATCH 发表于 2025-3-24 17:46:36
Active Iron-Oxo and Iron-Peroxo Species in Cytochromes P450 and Peroxidases; Oxo-Hydroxo Tautomerisoxylation, epoxidation, .- or .-oxide formation, etc.) which are mediated by an electrophilic oxidative species. The second class is represented by the oxidative deformylation of aldhehydes and involves a nucleophilic oxidant as active intermediate. The reductive activation of molecular oxygen by cyparagon 发表于 2025-3-24 21:08:11
Nucleophilicity of Iron-Peroxo Porphyrin Complexes,s. This review focuses on one of those postulated intermediates, the ferric heme peroxo complex, [(porphyrin)Fe(III)(O. .)]., a species which has been postulated to be formed transiently in the P450 catalytic cycle. Ferric peroxo porphyrin complexes, inorganic complexes that model the peroxo speciesantedate 发表于 2025-3-25 03:00:44
Characterization of High-Valent Oxo-Metalloporphyrins,s mediated by synthetic metalloporphyrins. In this review, we survey studies of high-valent oxo metalloporphyrins in the past decade. In Sect. 2, electronic structures and magnetic properties of compound I and compound II species in various heme enzymes are discussed on the basis of recent studies o