补角 发表于 2025-3-25 04:19:13
Principles in Organolanthanide Chemistry,lar emphasis is placed on synthetic aspects, i.e. optimization of established procedures and alternative methods with better access to catalytically relevant species. Accordingly, tailor-made ancillary ligands are reported in detail and the reactivity pattern of lanthanide compounds is examined with representative examples.Pelvic-Floor 发表于 2025-3-25 11:14:21
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Lanthanide Triflate-Catalyzed Carbon-Carbon Bond-Forming Reactions in Organic Synthesis,. A catalytic amount of Ln(OTf). is enough to complete reactions in most cases. In addition, Ln(OTf). can be recovered after reactions are completed and can be reused. Several chiral lanthanide catalysts for asymmetric Diels-Alder, aza Diels-Alder, and 1,3-dipolar cycloaddition reactions are also described.peritonitis 发表于 2025-3-25 22:23:46
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Influence of Solvents or Additives on the Organic Chemistry Mediated by Diiodosamarium,arium; some metal salts in catalytic amounts may also strongly accelerate or modify reactions induced by diiodosamarium. Thanks to the above tuning of the diiodosamarium reactivity, rich and diversified organic transformations have been performed, some examples of which are presented.杂役 发表于 2025-3-26 10:09:25
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