prodrome 发表于 2025-3-23 13:10:50
Adsorption and Reaction of CO2 on Metal Surfaces. Detection of an Intrinsic Precursor to Dissociatio science /1–2/. ERTL and his group /3–5/ unambiguously showed by molecular beam and other experiments that CO oxidation on transition metal surfaces proceeds via a Langmuir-Hinshelwood mechanism rather than an Eley-Rideal mechanism. This implies that both reactants, CO and oxygen are adsorbed on the密切关系 发表于 2025-3-23 17:51:20
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Thermal and Non-thermal Activation of Si(100) Surface NitridationOne intriguing finding of many studies in this area is that unusually high temperatures are required for sustained reactivity and film growth. Thus, for example, silicon nitride film growth using the reaction of Si with NH. is carried out at temperatures of l000–1300K.. Intuitively one would expect吞下 发表于 2025-3-24 04:09:00
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Equilibrium and Non-equilibrium Effects in Adsorption-Desorption Kinetics: Influences of Interactionyer, the internal equilibration of surface layers, and of the microscopic dynamics of the gas-surface interaction can be clearly seen in many cases, even though they can mix and interfere as well. Thermodynamic influences become most obvious if detailed coverage dependences of desorption rate parameelectrolyte 发表于 2025-3-25 01:40:31
Kinetics and Dynamics of Gas-Surface Interaction: The Principles of Detailed Balance and Unitaritying particles. In all cases the principles of detailed balance and unitarity are very helpful in reducing the number, of independent parameters of the theory and as a check of the results of calculations and experiments.