harpsichord
发表于 2025-3-23 13:02:58
Halogen Bonding in Supramolecular Synthesis,n we need to be able to rank the relative structural importance of such interactions and build synthetic methods to utilize synthons which can operate side-by-side without interference. Halogen bonds have characteristics (strength and directionality) which potentially make them prime candidates as c
食料
发表于 2025-3-23 14:40:32
Anion Transport with Halogen Bonds,of biological and synthetic transport systems. Emphasis is on examples that explore interactions beyond the coordination with lone pairs or hydrogen bonds for the recognition of cations and anions, particularly cation-π and anion-π interactions, and on structural motifs that are relevant for transpo
Lucubrate
发表于 2025-3-23 18:11:03
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antecedence
发表于 2025-3-24 02:09:12
,σ-Hole Bonding: A Physical Interpretation,Coulombic in nature (which encompasses polarization and dispersion). The strength of σ-hole bonding increases with the magnitudes of the potentials of the positive σ-hole and the negative site; their polarizabilities must sometimes also be taken explicitly into account.
epidermis
发表于 2025-3-24 06:01:00
https://doi.org/10.1057/9780230504806 engineering strategies for the assembly of specific architectures in molecular solids are described in detail, and the utility of halogen bonds for the synthesis of co-crystals are addressed. Finally, the structural compatibility or competition between of halogen- and hydrogen bonds in the context of supramolecular synthesis are examined.
男生戴手铐
发表于 2025-3-24 07:29:43
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Myelin
发表于 2025-3-24 12:45:22
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Allege
发表于 2025-3-24 15:25:51
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昏暗
发表于 2025-3-24 20:07:57
https://doi.org/10.1007/978-1-4039-8223-0 pair-possessing atoms, anions, and π-systems. This ability is quite general and is shown by a wide diversity of halogenated compounds (e.g., organohalogen derivatives and dihalogens). According to the definition proposed by the International Union of Pure and Applied Chemistry, any attractive inter
craven
发表于 2025-3-25 00:05:01
Dennis P. Hupchick,Harold E. Cox planar. On the other hand, the configuration at S in H.S⋯ICF. and H.S⋯ICl is permanently pyramidal. Ab initio calculations of potential energy functions for inversion at O or S performed at the CCSD(T)(F12*)/cc-pVDZ-F12 level of theory confirmed these conclusions. Comparison of the intermolecular s