RACE 发表于 2025-3-28 14:56:18

https://doi.org/10.1007/978-3-642-50745-8n of complex molecular structures. Olefin metathesis is indeed particularly suited for the construction of small open-chain molecules and macrocycles using crossmetathesis and ring-closing metathesis, respectively. These reactions serve, ., as key steps in the synthesis of various agrochemicals and

半导体 发表于 2025-3-28 22:45:33

Entwurfsbearbeitung und Modellversucheons are used to rationalize the complex mechanistic pathway from the starting precatalyst to the experimentally characterized decomposition products. In particular, we show that all the intermediates proposed by Grubbs and coworkers are indeed possible intermediates in the deactivation pathway, alth

ADOPT 发表于 2025-3-29 00:55:09

https://doi.org/10.1007/978-3-322-90091-3. We demonstrate that the PM6 method reproduces with interesting accuracy the geometries located with a DFT approach. As for the energetics, the relative DFT stability of the metallacycle with respect to the coordination intermediate is reproduced with reasonable accuracy by the PM6 method, whereas

彻底明白 发表于 2025-3-29 06:00:50

https://doi.org/10.1007/978-3-030-04933-1eculiar architecture of the dienyne precursor, exhibiting both a 1,6- and a 1,5-enyne skeleton, leads, in the presence of alkynophilic gold catalysts, to a mixture of bicyclic compounds. DFT calculations are presented that rationalize in full THE manifold of reactions that lead to the different prod

COKE 发表于 2025-3-29 08:47:24

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Merited 发表于 2025-3-29 11:50:09

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负担 发表于 2025-3-29 16:43:54

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慢跑 发表于 2025-3-29 21:16:04

Valerian Dragutan,Albert Demonceau,Eugene Sh. Fink

EXALT 发表于 2025-3-30 03:55:59

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FLINT 发表于 2025-3-30 07:24:49

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