conflate 发表于 2025-3-25 04:39:00
Estimates of Thermochemical Data for Organometallic Compounds,Literature methods that have been used to estimate the energetics of organometallic reactions are critically surveyed and illustrated with selected examples.四牛在弯曲 发表于 2025-3-25 10:55:51
http://reply.papertrans.cn/31/3100/309996/309996_22.png吗啡 发表于 2025-3-25 14:59:24
Selbstbestimmt bis nach dem Tods are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.Oration 发表于 2025-3-25 18:22:14
Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins,s are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.本土 发表于 2025-3-25 20:10:14
978-94-010-5088-3Springer Science+Business Media Dordrecht 1992凶猛 发表于 2025-3-26 01:01:28
http://reply.papertrans.cn/31/3100/309996/309996_26.png处理 发表于 2025-3-26 06:26:10
,Warum brauchen Verkäufer Selbst-PR?,nterest of thermochemists. Organometallic compounds were then of minor interest, and few such data had been measured. The development later of rotating bomb calorimetry, the use of combustion aids, advances in solution reaction calorimetry, and in particular, the adaptation of the Calvet twin-microcAXIOM 发表于 2025-3-26 09:36:27
,Die Logik der bürgerlichen Demokratie,ent 5f as well as tetravalent (d°) group 4 complexes, patterns in metal-ligand o bond enthalpies are rather similar for a diverse range of ligands. This information is directly applicable to the analysis and invention of a variety of stoichiometric and catalytic transformations, including olefin hyd薄膜 发表于 2025-3-26 13:12:35
https://doi.org/10.1007/978-3-531-19691-6centers. Advances have been made in both understanding the interactions of hydrocarbons with metals and in the energetics of these interactions. We have examined reactions of a series of arenes with (C.Me.) Rh(PMe.) PhH and begun to map out the kinetic and thermodynamic preferences for arene coordin半球 发表于 2025-3-26 16:53:45
Selbstbestimmt bis nach dem Tods are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.