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Sabine Verheyen,Katharina Riekeoncentration change stated above. This means that the thermodynamic behaviour of the electrons in α-Ag.S cannot be understood on the basis of the Boltzmann approximation. It is, however, possible to explain their behaviour quantitatively if the electrons are assumed to be degenerate thus making theamnesia 发表于 2025-3-22 22:36:18
https://doi.org/10.1007/978-3-322-92969-3 possible because galvanic cells containing solid auxiliary electrolytes, which exhibit virtually pure ionic conductivity, not only provide thermodynamic information via the emf but also allow direct determination of reaction rates via measurements of the current flow within a suitably constructed c死亡率 发表于 2025-3-23 02:49:25
Introduction,s reaction energies, reaction enthalpies and entropies, and also about activities, chemical potentials and partial pressures. From the kinetic point of view it is important that the current through suitably built galvanic cells with solid electrolytes can be a measure of reaction rates. The combinat蔓藤图饰 发表于 2025-3-23 06:14:58
Thermodynamic Quantities of Quasi-Free Electrons and Electron Defects in Semiconductors,ion band etc. In the course of the treatment of phase boundaries or surfaces we shall also discuss the terms work function, Volta potential and Galvani or macropotential. A detailed treatment of the band model of crystalline solids is beyond the scope of this book, and we refer readers to the accoun