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Electrochemical reactions of organosilicon compounds,oth anodic oxidation and cathodic reduction. Halosilanes are rather inert to electrochemical redox reactions and are often used as effective trapping agents of carbanion intermediates generated by cathodic reduction of organic halides. However, in the absence of other reducible substrates, halosilan
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Electrochemistry V978-3-540-48324-3Series ISSN 0340-1022 Series E-ISSN 1436-5049
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https://doi.org/10.1007/3-540-57729-7Elektrochemie; Ion; chemical reaction; electrochemistry; synthesis
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Invariants of Measure and Category,eactions were not recognized as a notable method for fluoro organic synthesis until about ten years ago. This review deals with the recent remarkable advances in electrochemical methods for the conversion and functionalization of fluoro organic molecules. The effect on fluorine atoms on the reductio
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Handbook of Settings-Based Health Promotionhibit unique electrochemical activitv. Upon α-substitution, silyl groups have electron-accepting effects and upon β-substitution, silyl groups have electron-donating effects to π systems. Silyl groups also have electron-donating effects to β-situated heteroatoms such as oxygen, nitrogen, and sulfur.
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