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Self-Assembled Coordination Cages and Organic Capsules as Catalytic Supramolecular Reaction Vesselseparation of many artificial host molecules that are not only capable of encapsulating a variety of guests but also of promoting reactions inside their cavities. As the environment dramatically influences the behavior of chemical systems, recent years have seen increased interest in the use of the sallergen 发表于 2025-3-22 00:33:28
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Catalysis Inside Folded Single Macromolecules in Water,trates into products. In contrast, synthetic polymers typically adopt random coil conformations in dilute solution or, in poor solvents, dense globular structures. Yet, the capability to control the global conformation of a synthetic polymer opened up many new applications that result from a three-dAdj异类的 发表于 2025-3-22 15:38:22
Microgel Star Polymer Catalysts as Active and Functional Nanoreactors for Organic Reactions and Polizations. Microgel star polymers are soluble core-shell gels consisting of a covalently crosslinked microgel core that is covered by multiple linear arm chains. The central cores thus serve as nano-confined spaces for various applications. Actually, microgel star polymers are effective as polymericAdj异类的 发表于 2025-3-22 19:10:10
Core-Cross-Linked Micelles and Amphiphilic Nanogels as Unimolecular Nanoreactors for Micellar-Type, exemplified by the large-scale Rhône-Poulenc/Ruhrchemie hydroformylation process, but can only be applied when the substrate is sufficiently soluble in the aqueous phase to sustain sufficiently fast mass transport. Different solutions to reduce mass transport limitations include the use of additivemembrane 发表于 2025-3-22 23:53:15
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