phytochemicals 发表于 2025-3-28 16:12:09
http://reply.papertrans.cn/31/3007/300638/300638_41.pngcipher 发表于 2025-3-28 22:16:26
Thermodynamik chemischer Reaktionen,ces, we shall present here the spectra of the vanadyl and thiovanadyl(IV) 2,3,7,8,12,13,17,18, octaethylporphyrin (V=O:OEP, V=S:OEP). As a typical illustration of the so-called focusing effect in the colinear arrangement of two scatterers we shall also reproduce the EXAFS spectrum of the dibromovanadium(IV) OEP complex.Somber 发表于 2025-3-29 02:09:22
0172-6218 s now diffi cult to keep up with the literature. EXAFS and XANES are becoming interdis ciplinary methods used in solid-state physics, biology, and chemistry, and are making impressive contributions to these branches of science. The present book gives a panorama of the research activity in this fieAORTA 发表于 2025-3-29 03:34:16
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https://doi.org/10.1007/978-3-642-52708-1lues. Thirdly, they continue to give insight into the important physical processes involved in EXAFS. Prior to using ab initio calculations in structural determinations, it is important to have some guidelines within which we can trust the results.制造 发表于 2025-3-29 15:17:41
The Transition Region Between XANES and EXAFS structural sensitivity is an electron emitted from an inner shell: the scattering of this electron modulates the absorption cross section. Figure 1 shows a typical X-ray absorption cross section and makes the somewhat arbitrary distinction between X-ray absorption near edge structure (XANES) and th讥笑 发表于 2025-3-29 16:53:14
Bond Angle Determination by EXAFS: A New Dimensionibution functions (distances), angular information is generally not available; except, perhaps, for polarization dependent measurements on single crystals. Furthermore, the very same advantageous characteristics of EXAFS (short-range, single-scattering) are also its serious limitations: distance detStress 发表于 2025-3-29 23:13:57
Role of Inelastic Effects in EXAFSch give an energetic photoelectron a short mean free path. The need for including inelastic damping effects in calculations of EXAFS spectra .(.) is graphically illustrated by a comparison of typical results of one-electron theory and experiment (Fig.1).欢腾 发表于 2025-3-30 02:03:31
http://reply.papertrans.cn/31/3007/300638/300638_49.png有帮助 发表于 2025-3-30 04:48:29
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