善于
发表于 2025-3-23 13:18:12
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Enthralling
发表于 2025-3-23 15:31:12
https://doi.org/10.1007/978-3-662-35216-8les other than NHCs might also induce this transformation. Further investigations showed that a catalytic amount of phosphine or 4-(.-dimethylamino)pyridine (DMAP) also promoted migrative cyclization in an a. Umpolung manner similarly. Furthermore, asymmetric induction was observed when a chiral DMAP derivative was used in the reaction.
WITH
发表于 2025-3-23 21:50:30
Die Zeit als Tatbestandsmerkmalas fount to give similar results with NHC. The possibility of enantiocontrol of this reaction was indicated by the use of chiral phosphine and binaphthyl-based chiral DMAP. Further investigation on developing an efficient enantioselective variant is currently in progress in this laboratory.
水獭
发表于 2025-3-24 00:00:15
https://doi.org/10.1007/978-981-13-9398-3Chiral Recognition; N-heterocyclic Carbine; Heterocycle Formation; Kinetic Resolution; Chiral Recognitio
上流社会
发表于 2025-3-24 04:40:54
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syring
发表于 2025-3-24 09:17:16
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合法
发表于 2025-3-24 13:22:21
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neurologist
发表于 2025-3-24 16:16:38
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冷漠
发表于 2025-3-24 21:39:39
https://doi.org/10.1007/978-3-662-35216-8ompanied 1,2-migration of the sulfonyl groups. This reaction provides a novel access to oxa- and azacycles possessing a pendant vinyl sulfone functionality, which in turn is amenable to further transformations. During research on this migrative cyclization, mechanism studies indicated that nucleophi
excrete
发表于 2025-3-25 00:01:12
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