行为 发表于 2025-3-26 21:38:56
Racemizations of Alkyl Groups in Cobaloxime Complex Crystals,ng the size and shape of the reaction cavity. For the bulkier (methoxycarbonyl)ethyl groups, not only the inversion of the chiral carbon atom bonded to the cobalt atom but also the .. transformation of the methoxyl group occurs cooperatively. Moreover, solvent molecules in a crystal play an important role in racemization.嫌恶 发表于 2025-3-27 02:48:32
Characteristic Processes of Various Racemizations,up. For the 1,2-bis(ethoxycarbonyl)ethyl group, only the two bonds connecting the chiral carbon of the produced radical rotated and opposite side of the radical made a bond to the cobalt atom. Such a two-bond rotation, which is called “hula-twist” as observed in rhodopsin, may be caused by long substituents bonded to the carbon radical.FACT 发表于 2025-3-27 06:06:38
Chapter 4: Action and the Pragmatic Maximl group, the . isomerization occurs with retention of the single crystal form. For the 3-butenyl group, the . isomerization does not occur, keeping the single crystal form, although the isomerization occurred in the solid state.neutrophils 发表于 2025-3-27 10:51:15
http://reply.papertrans.cn/25/2407/240655/240655_34.png人类的发源 发表于 2025-3-27 14:30:01
http://reply.papertrans.cn/25/2407/240655/240655_35.png搬运工 发表于 2025-3-27 21:41:26
http://reply.papertrans.cn/25/2407/240655/240655_36.png贪婪地吃 发表于 2025-3-27 23:04:53
Book 2014d state reaction, in which a reaction occurs with retention of the single crystal form. The whole reaction processes were observed directly by X-ray and neutron diffractions. In this book, not only the structures of metastable intermediates, such as radicals, carbenes, and nitrenes, but also the unsCULP 发表于 2025-3-28 02:33:54
Crystalline-State Reaction and Reaction Cavity, to estimate the void space around the reactive group. For the crystalline-state reaction, it was easy to understand the way how the void space is effectively utilized in the process of the reaction, comparing the void space before and after the reaction.granite 发表于 2025-3-28 10:08:52
http://reply.papertrans.cn/25/2407/240655/240655_39.pngPruritus 发表于 2025-3-28 13:05:25
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