athlete’s-foot 发表于 2025-3-28 18:07:31
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Experimental Observation of Electron Spin Polarization in Reactions,The different types of experiments in which Chemically Induced Dynamic Electron Polarization (CIDEP) has been observed are described. Two distinct types of spin polarization are recognised and reported results are interpreted in terms of various admixtures of these two types. Reasons why one or the other predominates in a given case are suggested.表状态 发表于 2025-3-29 05:36:30
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The Problem of Parallel Radical and Non-Radical Mechanisms,The most commonly expressed concern about the utility of CIDNP in mechanistic chemistry is a reservation about whether the radical pathway which it reveals is the sole pathway for producing the observed products.Magnificent 发表于 2025-3-29 12:46:00
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CIDNP Exhibited by Thermally Decomposing Diacyl Peroxides,nts and may be decomposed thermally at temperatures sufficiently high to permit their isolation and purification, but low enough to be accessible with routinely available nmr variable temperature accessories. Equally important, however, is the well defined radical pair initially formed from the deco