Evolve 发表于 2025-3-23 12:53:16

Alberto Distefano,Lindsay Rothfield,Jia Xuate, the overall rate (1n the absence of diffusion limitations) is determined by the rate of electron transfer, and the subsequent chemical reaction does not affect the kinetics of the electrode process at all.

Toxoid-Vaccines 发表于 2025-3-23 13:56:58

https://doi.org/10.1007/978-3-031-27825-9 equal to -0.21 V (versus a normal hydrogen electrode); for copper, -0.04 V; zinc, -0.66 to -0.69 V. The most negative E. values are for Na (-1.7 to -1.9), Cd (-0.74 to -0.9), and Tl (-0.65 to -0.86 V).

伪善 发表于 2025-3-23 19:56:38

Currents Limited by the Rate of Chemical Reaction,at the electrode surface. With kinetic currents the chemical reactions can take place before the electron transfer, can follow the electron transfer, or may take place parallel with the electrochemical stage. Accordingly, the kinetic waves can be classified into waves corresponding to antecedent, successive, or parallel chemical reactions .

周兴旺 发表于 2025-3-23 23:38:37

Adsorption on the Electrode and the Electrode Processes,e; Γ. is the quantity of adsorbed compound if the surface is completely covered by a monomolecular layer; c is the concentration of the adsorbed compound in the bulk solution (M); and . is the adsorption coefficient (M.).

灾难 发表于 2025-3-24 05:57:49

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Crater 发表于 2025-3-24 09:32:47

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COWER 发表于 2025-3-24 12:18:44

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Wernickes-area 发表于 2025-3-24 17:48:47

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RODE 发表于 2025-3-24 19:04:41

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Dissonance 发表于 2025-3-25 02:54:18

Orvar Löfgren,Barbara CzarniawskaLet us consider the electrochemical process of reduction of compound A to compound B.where n is the number of electrons taking part in this process, and k. and k. are the heterogeneous rate constants of the forward and reverse electrochemical reaction (cm/sec).
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查看完整版本: Titlebook: Catalytic and Kinetic Waves in Polarography; Stal’ G. Mairanovskii Book 1968 Springer Science+Business Media New York 1968 Sorption.adsorp