gangrene 发表于 2025-3-30 10:16:00
Introduction,n this field of organic chemistry, especially in the last 10 years, there is a need for giving an update and summarizing the existing differing aldol methodologies. This is of particular importance in the field of organocatalysed aldol addition.旧石器时代 发表于 2025-3-30 16:25:06
Magnesium Enolates,nolates in stereoselective aldol additions was reported by Solladie and coworkers.. Deprotonation of sulfinyl acetate with .-butylmagnesium bromide yielded aldol adducts with moderate to high enantioselectivities (Scheme 2.2.1).Pathogen 发表于 2025-3-30 17:31:10
Silver, Palladium and Platinum Lewis Acids,agisawa and coworkers developed an enantioselective Mukaiyama aldol approach based on the deployment of .-Tol-BINAP—AgF. Trimethoxysilyl enol ethers of ketones were reacted with non-enolizable aldehydes. The corresponding .-configured aldol adducts were isolated with excellent enantioselectivities (Scheme 3.1.5.1)..换话题 发表于 2025-3-30 23:34:09
http://reply.papertrans.cn/16/1524/152329/152329_54.pngPALL 发表于 2025-3-31 03:02:37
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Miscellaneous Lewis Acids,By application of copper or tin Lewis acids in Mukaiyama aldol reactions mostly .-configured aldol adducts of enolsilanes, pyruvates and glyoxylates electrophiles were detected. In contrast to that scandium complexes proved to be effective catalysts in .-selective aldol additions of enolsilanes and ethylglyoxylate (Scheme 3.1.7.1)..grandiose 发表于 2025-3-31 12:08:20
Undergraduate Texts in Computer Sciencen this field of organic chemistry, especially in the last 10 years, there is a need for giving an update and summarizing the existing differing aldol methodologies. This is of particular importance in the field of organocatalysed aldol addition.PHAG 发表于 2025-3-31 13:23:48
http://reply.papertrans.cn/16/1524/152329/152329_58.pnginduct 发表于 2025-3-31 21:09:31
http://reply.papertrans.cn/16/1524/152329/152329_59.png施魔法 发表于 2025-4-1 01:15:09
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