Ptsd429 发表于 2025-3-23 12:24:22
http://reply.papertrans.cn/15/1490/148901/148901_11.pngchampaign 发表于 2025-3-23 15:02:34
http://reply.papertrans.cn/15/1490/148901/148901_12.pngbeta-cells 发表于 2025-3-23 22:04:29
Preparing the Collaborative Classed that the C-F bond in . readily reacts with HBF. in the presence of protic nucleophiles such as alcohols and thiols to give carbene complexes. The intermediacy of an hydridodifluorocarbene species has been confirmed by low-temperature NMR spectroscopy.The X-ray structure of an hydridocarbene complmalign 发表于 2025-3-23 22:54:25
http://reply.papertrans.cn/15/1490/148901/148901_14.pngblister 发表于 2025-3-24 02:22:00
http://reply.papertrans.cn/15/1490/148901/148901_15.pngEntrancing 发表于 2025-3-24 06:59:34
http://reply.papertrans.cn/15/1490/148901/148901_16.png飞镖 发表于 2025-3-24 12:40:42
http://reply.papertrans.cn/15/1490/148901/148901_17.png性冷淡 发表于 2025-3-24 17:09:03
http://reply.papertrans.cn/15/1490/148901/148901_18.pngExternalize 发表于 2025-3-24 20:36:45
Collaboration in a Hyperconnected Worldcationic carbene Cp.Fe.(CO).(μ-CO) [μ-C(CN) (SMe.)]... probably via migration of SMe. to the μ-carbon atom. The sulfonium complex . is also obtained by reacting the cyano(thiolkoxy)-methylene derivative Cp.Fe.(CO).(μ-CO) [μ-C(CN)SMe], ., with MeSO.CF.. The cyanocarbyne-like carbon in . is attacked b羽饰 发表于 2025-3-25 01:42:12
Dario Antonelli,Sergey Astanin,Giulia Brunocyclopentylidene)chromium complexes (3a-f) through the ring opening of oxiranes by the conjugate base of the pentacarbonyl(methoxymethylcarbene)chromium complex (1); oxidation of (3a-f) with Ce. leads to the corresponding γ-lactones. The extension of the above reactions to oxetane allowed the synthe